YAO Meng, SUN Yaqiao, LI Wanpeng, DOU Lin
Based on the leaching experiment of the sediments in Weihe River at Xianyang section(midstream) and Weinan section(downstream)under the condition of water renewal and the hydrogeochemical simulation, three eigenvalues, the change rule of eight water chemical constitutes and the change characteristics of the saturation indexes of five mineral substances were analyzed in this research. The results showed that the conductivity, Eh and Ph of the lixivium presented fluctuant ascending trend with the increase of water renewal volume. Concerning the change trend of the conductivity, Xianyang section was more significant than that of Weinan section, and the change trend of Eh, Weinan section was more significant than that of Xianyang section, indicating that the sediments at the downstream of Weihe River have finer grains and higher reducibility. The lixivium gradually transformed from weakly acid to weakly alkaline. The concentrations of HCO3-, Cl-, SO42- presented a changing process from fast increase and gradual decrease and then to the stable state with the increase of water renewal volume, and the rangeability at Xianyang section was much higher. The concentrations of CO3 2-showed a decreasing trend. With the increase of water renewal volume, the concentrations of Ca2+;Mg2+, Na+ and K+ quickly increased firstly and then to the stable state, and the initial concentrations and the rangeability of these substance at Xianyang section were higher than those at Weinan section. The saturation indexes of anhydride and gypsum in the lixivium presented the same change trend with the increase of water renewal volume, and the saturation indexes were less than zero. When the water renewal volume was less than 22.5%, Xianyang section had the strongest dissolving capacity;when the water renewal volume was more than 22.5%, it began to saturate and precipitate. When the water renewal volume was by 12.5%, Weinan section presented the lowest saturation index; when it got to more or less than 12.5%, the saturation index presented the slow increasing trend. The saturation indexes of calcite and dolomite also presented the same change trend with the increase of water renewal volume, and the saturation indexes were more than 0. When the water renewal volume was less than 12.5%, Xianyang section had the stronger dissolving capacity;when the water renewal volume was more than 12.5%, it began to saturate and precipitate. When the water renewal volume was less than 5%, Weinan section had the stronger dissolving capacity;when the water renewal volume was more than 5%, it began to saturate and precipitate. When the water renewal volume was more than 10%, the saturation index of NaCl got to the maximum;and when the water renewal volume was more than 15%, it began to precipitate. The saturation indexes of the five mineral substances in the sediments of Xianyang section were higher than those of Weinan section respectively, indicating that the dissolving capacity of the mineral substances at the midstream of Xianyang section in Weihe River was lower than that of the downstream Weinan section under the condition of water renewal, and the precipitation capacity and volume of Xianyang section were much higher.