ZHANG Yange, XU Jianzhong, YU Guangming
In order to investigate the characteristics of water-soluble ions in atmospheric particles in northeast margin of the Tibetan Plateau, a field study was carried out at the Qilian Shan Station of Glaciology of Ecologic Environment from 16 July to 11 August, 2016. A total of 13 PM2.5 filter samples and 4 sets of size-segregated aerosol samples had been taken. Results indicated that sum of total water-soluble ions concentrations was 2.35 μg·m-3 in non-dust period, which was slightly higher than the results observed in 2012, with the concentrations of SO42-, Ca2+, NH4+, NO3- being 1.28, 0.33, 0.32, and 0.28 μg·m-3, accounting for 94% of the total water-soluble ions. The sum of total water-soluble ions concentrations was 12.63 μg·m-3 in dust period, which was five times of that in non-dust period, with the concentrations of SO42-, Ca2+, Cl-, Na+, NO3- in this period being 5.36, 4.77, 0.80, 0.62, 0.61 μg·m-3, accounting for 96% of the total water-soluble ions. From the analysis of size-segregated samples, one can see that NO3- was mainly distributed in the coarse mode, probably formed by the heterogeneous reaction of precursors on surface of atmospheric particles. In all periods, SO42- shows an obvious peak in the coarse mode at size bin of 1.8~3.2 μm, mainly from mineral dust and in non-dust period, SO42- also shows a significant peak in the accumulation mode at the size bins of 0.18~0.32 μm or 0.32~0.56 μm, formed from secondary chemical reactions. The estimated contribution of the secondary chemical reactions to SO42- is 80%.