XU Jian-zhong, SUN Jun-ying, REN Jia-wen, QIN Da-he
Marine aerosol samples are collected on the route of the Second Chinese National Article Research Expedition from July 15 to September 28, 2003. The concentrations of water soluble ions (Na+、NH4-、Ca2+、Cl-、 MSA 、 SO42- and so on) are obtained. By correlation analysis, the ions can be divided into three groups: 1) Na+, Mg2+, K+, Ca2+, Cl-, SO42-, mainly from sea salt; 2) NH4-, NO3-, markedly from coastal regions of the continents; 3) Ace, MSA, C2O42-, from other sources. Marine aerosols are the dominant ions, Cl- and Na+ are the most dominant anions and cations, and these two ions (Na+~Cl-) account for 60.2% of the total aerosol load. The mean ratio of NH4-/SO42- is 0.45. Based on the balance between ions and environment, it is suggested that ammonium and sulfate exist mainly in the form of NH4HSO4. According to the concentration of NO3-, the expedition route may be divided into three parts: Japan Sea with a NO3- media value of 15.2 neq·m-3, Sea of Okhostk and Bering Sea with a NO3- media value of 1.8 neq·m-3 and Arctic Ocean with a NO3- media value of 0.4 neq·m-3. Comparing the concentrations of main water-soluble ions between the First and Second Chinese National Arctic Research Expedition, it is found that the two concentrations are basically identical, the mean concentration of Na+ is 36.3 and 36.2, and that of SO42- is 17.7 and 22.1, respectively. The highest MSA appears in the Bering Sea. The concentrations of the two NO3-’s series are quite identical, so it can be taken as an indicator of anthropogenic activity.