SUN Jun-ying, QIN Da-he, REN Jia-wen, LI Zhong-qin, HOU Shu-gui
Aerosol, precipitation, snow and runoff samples were collected from the headwaters of the Ürüqi River from May to June 1996. The measurement of major anions and cations (Cl-, NO3-, SO42-, Ca2+, Mg2+, Na+, K+, NH4+), and pH has been made for these samples, except that ammonium has not been done for precipitation samples. pH measurements show that snow and precipitation samples are near to neutral while runoff samples are slightly alkaline. It is found that the sum of measured cations is 2 to 8 fold of measured anions in equivalent unit for aerosol, precipitation, snow and runoff samples. The fact that the measured cations in aerosol exceed the measured anions also suggests that the atmosphere is alkaline over the glacier. According to the previous studies over this area, the missing anion is assumed to be bicarbonate. Thus, bicarbonate and calcium are the dominant anion and cation, respectively, for aerosol, precipitation, snow and runoff samples in this area. The total ionic concentration in various waters is in the order: runoff below the Glacier No. 1>runoff at the control point>runoff below the ice free cirque>precipitation>snow. However, the order of the concentration for different ions is not the same for these waters and aerosol, e.g., Ca2+ >Mg2+ > Na+ >K+ >NH4+ for snow and runoff samples, Ca2+ >Na+ >Mg2+ >K+ for aerosol and precipitation samples, while HCO3->SO42-> Cl- >NO3- for aerosol, precipitation, runoff below the Glacier No. 1 and at the control point, HCO3->Cl- >SO42->NO3- for snow and below the ice free cirque. Through the comparison of ionic concentration in different waters, the effect of some processes, such as wet deposition, dry deposition, preferential elution etc, on the certain ionic concentration in the waters is revealed. For example, preferential elution results in lower concentration of SO42- and NO3- and dry deposition enhances concentration of Mg2+, Ca2+ and K+ in snow.